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說說聚乳酸纖維

發(fā)布時間：2023-02-12 08:31:00 點擊：

1 什么是聚乳酸纖維

卷染機(jī)專業(yè)生產(chǎn)廠家無錫金潤達(dá)2023年2月12日訊 聚乳酸纖維是以玉米、小麥、甜菜等含淀粉的農(nóng)產(chǎn)品為原料，經(jīng)發(fā)酵生成乳酸后，再經(jīng)縮聚和熔融紡絲制成.聚乳酸纖維，是一種原料可種植、易種植，廢棄物在自然界中可自然降解的合成纖維。它在土壤或海水中經(jīng)微生物作用可分解為二氧化碳和水，燃燒時，不會散發(fā)毒氣，不會造成污染，是一種可持續(xù)發(fā)展的生態(tài)纖維。其織物面料手感、懸垂性好，抗紫外線，具有較低的可燃性和優(yōu)良的加工性能，適用于各種時裝、休閑裝、體育用品和衛(wèi)生用品等，具有廣闊的應(yīng)用前景。

2 聚乳酸纖維的特性

2.1可生物降解性

PLA纖維具有良好的可生物降解性，被廢棄后可在自然界中完全分解為 CO2 和 H2O。二者通過光合作用，又可變成乳酸的原料——淀粉。PLA 纖維如果與其它有機(jī)廢棄物一同掩埋，幾個月內(nèi)便會分解，可以完全分解成 CO2 和 H2O。對人體而言都是無毒的，沒有致癌作用，更安全，因而在生物醫(yī)療領(lǐng)域的應(yīng)用極為廣泛。

2.2物理機(jī)械性能

PLA 在所有生物可降解聚合物中，熔點最高、結(jié)晶度大、透明度好，很適合于制作纖維、薄膜及模壓制品。PLA 纖維的物理性能接近 PET 纖維 (滌綸)和 PA 纖維(尼龍)，染色性能優(yōu)于 PET 纖維。PLA 纖維不僅具有高結(jié)晶性，還具有同樣的透明性；并且由于它的高結(jié)晶性和高取向度，從而具有高耐熱性和高強(qiáng)度，且無需特殊的設(shè)備和操作工藝，應(yīng)用常規(guī)的加工工藝便可進(jìn)行紡絲。

2.3較好的熱穩(wěn)定性

聚乳酸纖維具有較好的熱穩(wěn)定性，其玻璃化溫度為 57℃，熔融溫度為 175℃。熱分解溫度為 200℃左右。其染色性能優(yōu)于滌綸纖維，雖染色須采用分散染料，但不需要高溫高壓。

2.4化學(xué)性能

聚乳酸纖維具有較好的耐酸性，具有天然乳酸性。不溶于醇類和醚類溶劑中，溶解于丙酮、氯仿等有機(jī)溶劑中，對堿的抵抗能力較差。自身酸堿度與人體 PH 值極為接近，所呈現(xiàn)的天然抗敏親膚功能，相當(dāng)于人體的第二層皮膚，特別適合于各類親膚產(chǎn)品。

2.5安全性

由于 PLA 纖維具有生物相容性，且服用舒適，可安全植入體內(nèi)，無毒副作用。

2.6耐氣候性

PLA 纖維在室外暴曬 500 h 后，強(qiáng)度可保留 55 %左右。

2.7原料來源豐富

生產(chǎn) PLA 的原料豐富，例如甜菜、玉米等，并且可通過不斷種植獲得這些原料。由于不采用石油或木材，這對于有限的石油和木材資源將起到保護(hù)作用。聚乳酸的原料是乳酸，即-羥基丙酸、2-羥基丙酸。由于乳酸分子中有一個不對稱碳原子，所以具有 d-型（右旋光）和 L-型（左旋光）兩種對映體，等量的 L-乳酸和 d-乳酸混合而成的 dL-乳酸不具旋光性。成纖聚乳酸以L-乳酸為單體。

3聚乳酸纖維的發(fā)展前景

在供給方面，2020 年全球聚乳酸產(chǎn)能近 40 萬噸，目前美國Nature Works 公司是全球最大的生產(chǎn)商，產(chǎn)能占比達(dá) 40%；而我國聚乳酸的生產(chǎn)仍處于起步階段。在需求方面，2019 年，全球聚乳酸市場規(guī)模已達(dá) 6.608 億美元，預(yù)計 2021-2026 年期間，全球市場將保持 7.5%的年均復(fù)合增速增長。

隨著國內(nèi)改性及共混技術(shù)的發(fā)展，生物基塑料在硬度、力學(xué)強(qiáng)度、耐熱性、透明度等性能指標(biāo)方面已接近傳統(tǒng)石油基塑料，我國 PLA 纖維產(chǎn)業(yè)正進(jìn)入蓬勃發(fā)展時期。作為傳統(tǒng)缺乏競爭力的石油基塑料替代品，聚乳酸有著非?？捎^的應(yīng)用前景。

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